Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of o-Phenylenediamine (OPD) (CAS: 95-54-5) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase o-Phenylenediamine, Please contact: alvin@ruifuchem.com
o-Phenylenediamine (OPD) | CAS 95-54-5 |
p-Phenylenediamine (PPD) | CAS 106-50-3 |
m-Phenylenediamine (MPD) | CAS 108-45-2 |
Chemical Name | o-Phenylenediamine |
Synonyms | 1,2-Phenylenediamine; 1,2-Diaminobenzene; 1,2-Benzenediamine; o-Benzenediamine; o-Diaminobenzene; OPD |
Stock Status | In Stock, Production Capacity 7000 Tons per Year |
CAS Number | 95-54-5 |
Molecular Formula | C6H8N2 |
Molecular Weight | 108.14 g/mol |
Melting Point | 99.0~103.0℃ |
Boiling Point | 256.0~258.0℃ |
Flash Point | 110℃ |
Density | 1.27 g/cm3 |
Sensitive | Light Sensitive, Air Sensitive |
Water Solubility | Soluble in Water, 41 g/l 35℃ |
Solubility | Very Soluble in Ether, Chloroform, Alcohol. Soluble in Acetone, Benzene |
Stability | Stable. Incompatible with Strong Oxidizing Agents. |
COA & MSDS | Available |
Sample | Available |
Origin | Shanghai, China |
Brand | Ruifu Chemical |
Items | Specifications | Results |
Appearance | White to Off-White to Light Brown Crystals or Flakes | Complies |
Melting Point | 99.0~103.0℃ | 101.7~102.3℃ |
Purity / Analysis Method | ≥99.5% (HPLC) | 99.9% |
Water by Karl Fischer | ≤0.50% | 0.21% |
o-Chloroaniline | ≤0.03% | Complies |
o-Nitroaniline | ≤0.03% | Complies |
p-Phenylenediamine | ≤0.03% | Complies |
m-Phenylenediamine | ≤0.03% | Complies |
Total Impurities | ≤0.50% | Complies |
Infrared Spectrum | Consistent with Structure | Complies |
Conclusion | The product has been tested and complies with the given specifications |
Package: Bottle, Aluminium foil bag, 25kg/Bag, 25kg/Cardboard Drum, or according to customer's requirement.
Storage Condition: Keep the container tightly closed and store in a cool, dry and well-ventilated warehouse away from incompatible substances. Protect from light and moisture.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery.
How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.
Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.
Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.
Quality Assurance? Strict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.
Samples? Most products provide free samples for quality evaluation, shipping cost should be paid by customers.
Factory Audit? Factory audit welcome. Please make an appointment in advance.
MOQ? No MOQ. Small order is acceptable.
Delivery Time? If within stock, three days delivery guaranteed.
Transportation? By Express (FedEx, DHL), by Air, by Sea.
Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.
Custom Synthesis? Can provide custom synthesis services to best fit your research needs.
Payment Terms? Proforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc.
Risk Codes R20/21 - Harmful by inhalation and in contact with skin.
R25 - Toxic if swallowed
R36 - Irritating to the eyes
R40 - Limited evidence of a carcinogenic effect
R43 - May cause sensitization by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R68 - Possible risk of irreversible effects
Safety Description S28 - After contact with skin, wash immediately with plenty of soap-suds.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S1/2 - Keep locked up and out of the reach of children.
UN IDs UN 1673 6.1/PG 3
WGK Germany 3
RTECS SS7875000
FLUKA BRAND F CODES 8-10-23
TSCA Yes
HS Code 2921511000
Hazard Class 6.1
Packing Group III
Toxicity LD50 in rats (mg/kg): 1070 orally; 516 i.p., C. Burnett et al., J. Toxicol. Environ. Health 2, 657 (1977)
o-Phenylenediamine (OPD) (CAS: 95-54-5) is the simplest aromatic diamine. There are three isomers, namely o-Phenylenediamine, m-Phenylenediamine and p-Phenylenediamine. o-Phenylenediamine's color is easy to change upon exposure to air, from white to yellow, brown, purple, and finally into black.
o-phenylenediamine has active chemical properties, being able to have condensation reaction with acid, aldehydes, ketones and other compounds, generating heterocyclic compounds; it can also have oxidation, condensation, substitution and diazotization reaction.
Phenylenediamine is used as a fluorescent indicator and chromatographic analysis reagent. It is used for the identification of copper, gold, iron, magnesium, vanadium, ammonia, hydrogen sulfide, sulfur dioxide and chromic oxide, etc., and manufacturing azo dyes, fur dyeing and photographic materials. , Printing and dyeing industry.
1. It can be used as a cationic dye intermediates, being the main raw material of pesticides, carbendazim and other fungicides.
2. It can be used as analytical reagent, fluorescent indicator, also used in organic and dye synthesis. It can be used as an important intermediate in the manufacture of other fine chemicals, pesticides, pharmaceuticals and dyes, pigments, and fungicides, vulcanization accelerators for rubber, developers for the photographic industry, fur dyes and hair dyes. It is also used in hair dye formulation, as a photographic developing agent, and in organic synthesis.
3. Phenylenediamine is the intermediate of fungicide carbendazim, methyl thiophanate, and thiabendazole, but also insecticides quinalphos intermediates.
o-Phenylenediamine has moderate toxicity, often due to inhalation of dust or skin absorption caused by poisoning (the latter phenomenon mostly). Inhalation of dust can cause rhinitis, bronchitis, frequent fever, causing unique asthma and vagal nervous tension caused by the tracheal inflammation, can cause severe acute eczema and eczema. m-Phenylenediamine can cause methemoglobin changes, while the p-phenylenediamine can cause bronchial asthma, allergic dermatitis.
Category Toxic substances
Toxicity classification highly toxic
Acute toxicity Oral-Rat LD50: 1070 mg/kg; Oral-mouse LD50: 366 mg/kg
Flammability hazardous characteristics it is flammable with heating releasing toxic aniline gases
Storage and transportation characteristics Treasury: ventilated, low-temperature and dry; store it separately from food raw materials for storage and transportation
Fire extinguishing agent mist water, carbon dioxide, sand
Confirmed carcinogen. Poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. Mildly toxic by skin contact. Mutation data reported. A pesticide and pharmaceutical. When heated to decomposition it emits toxic fumes of NOx. See also other phenylenediamine entries and AMINES
UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.