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p-Phenylenediamine (PPD) CAS 106-50-3 Purity ≥99.5% (GC)

Ruifu Chemical is the leading manufacturer of p-Phenylenediamine (1,4-Phenylenediamine; PPD) (CAS: 106-50-3) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase p-Phenylenediamine, Please contact: alvin@ruifuchem.com

Chemical Name p-Phenylenediamine 
Synonyms 1,4-Phenylenediamine; para-Phenylenediamine; 1,4-Diaminobenzene; 1,4-Benzenediamine; Benzene-1,4-Diamine; PPD
Stock Status In Stock, Production Capacity 5000 Tons per Year
CAS Number 106-50-3
Molecular Formula C6H8N2
Molecular Weight 108.14 g/mol
Melting Point 138.0~143.0℃(lit.) 
Boiling Point 267.0~271.0℃(lit.)  
Flash Point 156℃(312°F)
Density 1.135 g/cm3 (20℃) 
Sensitive Light Sensitive, Air Sensitive 
Water Solubility  Soluble in Water, 40 g/l 25℃
Solubility  Soluble in Alcohol, Chloroform, Ether. Very Slightly Soluble in Benzene
COA & MSDS Available
Sample  Available
Origin Shanghai, China
Brand Ruifu Chemical
Items Specifications  Results
Appearance White to Grey Powder or Flakes  Complies      
Melting Point 138.0~143.0℃ 140.0~142.0℃
p-Phenylenediamine Purity  ≥99.5% (GC)  99.9% 
m-Phenylenediamine ≤0.04% <0.04%
o-Phenylenediamine ≤0.04% <0.04%
4-Chloroaniline ≤0.01% <0.01%
Ignition Residue (as Sulfate) ≤0.005% <0.005%
Infrared Spectrum Consistent with Structure Complies 
Conclusion The product has been tested and complies with the given specifications

Package: Bottle, Aluminium foil bag, 25kg/Bag, 25kg/Cardboard Drum, or according to customer's requirement.
Storage Condition: Keep the container tightly closed and store in a cool, dry and well-ventilated warehouse away from incompatible substances. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. Protection against heat, moisture and sun. According to the provisions of the storage and transportation of toxic and flammable chemicals.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery. 

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com 

15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.

Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.

Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.

Quality Assurance? Strict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.

Samples? Most products provide free samples for quality evaluation, shipping cost should be paid by customers.

Factory Audit? Factory audit welcome. Please make an appointment in advance.

MOQ? No MOQ. Small order is acceptable.

Delivery Time? If within stock, three days delivery guaranteed.

Transportation? By Express (FedEx, DHL), by Air, by Sea.

Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.

Custom Synthesis? Can provide custom synthesis services to best fit your research needs.

Payment Terms? Proforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

Risk Codes R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R36 - Irritating to the eyes
R43 - May cause sensitization by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R63 - Possible risk of harm to the unborn child
R36/37/38 - Irritating to eyes, respiratory system and skin.
R45 - May cause cancer
R40 - Limited evidence of a carcinogenic effect
R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed.
R67 - Vapors may cause drowsiness and dizziness
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description S28 - After contact with skin, wash immediately with plenty of soap-suds.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S28A -
S24/25 - Avoid contact with skin and eyes.
S23 - Do not breathe vapour.
S53 - Avoid exposure - obtain special instructions before use.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDs UN 1673 6.1/PG 3
WGK Germany 3
RTECS SS8050000
FLUKA BRAND F CODES 8-10-23
TSCA Yes
HS Code 2921519090
Hazard Class 6.1
Packing Group III
Toxicity LD50 in rats (mg/kg): 80 orally, 37 i.p. (Burnett)

p-Phenylenediamine (1,4-Phenylenediamine; PPD) (CAS: 106-50-3) is one of the simplest aromatic diamine. It has been described as gray “light brown” which may result from exposure to air. It can be used for making azo dyes, high-molecule polymers and can also be used for the production of fur dyes, rubber antioxidants and photo developer and is mainly used for Kevlar, azo dyes, sulfur dyes, acid dyes. It can also be used as the raw material of cosmetic hair p-Phenylenediamine series, gasoline polymerization inhibitor and developer. p-Phenylenediamine, as a chemical dye, is currently permitted for use in hair dye production, but there is a clear usage limits. Used as organic intermediates or pharmaceutical intermediates.

Dust may form explosive mixture with air. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates, and strong bases. Incompatible with organic anhydrides; isocyanates, aldehydes. Heat and light contribute to instability. Keep away from metals.  

UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.